EXO-2-NAPHTHYL KWON [2.2.1] BICYCLIC PHO

Code: 798347-100MG D2-231

Application

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines a...


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€119.10 100MG
€146.49 inc. VAT
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Application

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

Other Notes

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-PyrrolinesTechnology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from HydroxyprolineAldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

Packaging

100 mg in glass bottle

formpowder
InChI keySJQXCVUHXMHJMD-UHFFFAOYSA-N
InChI1S/C22H22NO2PS/c1-16-6-10-22(11-7-16)27(24,25)23-14-21-13-19(23)15-26(21)20-9-8-17-4-2-3-5-18(17)12-20/h2-12,19,21H,13-15H2,1H3
mp153-158 °C
Quality Level100
SMILES stringO=S(N1C[C@H]2[P@](C3=CC=C4C(C=CC=C4)=C3)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
storage temp.2-8°C
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